For more information on compiling GCC, do take a look at Compiling GNU 4.8.1 on CentOS 6
A quick look, shows that my .bashrc was incorrect written. My PATH and LD_LIBRARY_PATH should reflect the pathing of GCC
export PATH=$PATH:/usr/local/gcc-4.8.2/bin export LD_LIBRARY_PATH=$LD_LIBRARY_PATH:/usr/local/gcc-4.8.1/lib
Secondly, another possible issue could be due to incomplete or unlinked gfortran libraries. Do check with your /usr/local/gcc-4.8.1 that your libgfortran.so.3 is linked and present with the right libraries.
Lastly, you can force the OpenMPI to compile F77 and FC with the following configuration
# ./configure --prefix=/usr/local/openmpi-1.6.5-gcc-4.8.1 \ F77=gfortran FC=gfortran --with-devel-headers --enable-binaries
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